Basic functions: Power functions
Context 3: Solubility of chemical substances
A context in which you also encounter power functions is the heterogeneous equilibrium state of an electrolyte in a saturated aqueous solution.
Calcium fluoride dissolves only partially in water; it is an equilibrium reaction \[\mathrm{CaF}_2 (\mathrm{solid}) \rightleftharpoons \mathrm{Ca}^{2+}+2\mathrm{F}^{-}\] The solubility product \(K_s\) is equal to the product of the concentrations of the dissolved ions, with each concentration raised to a power with exponent equal to the stoichiometric coefficient of the ion involved in the ionization equation. In this case, we have: \[K_s=\left[\mathrm{Ca}^{2+}\right]\cdot \left[\mathrm{F}^{-}\right]^2\] Suppose that \(x\) mole per liter of calcium fluoride dissolves, then the following holds: \[\left[\mathrm{Ca}^{2+}\right]=x, \quad \left[\mathrm{F}^{-}\right]=2x\] and \[K_s=x\cdot (2x)^2=4x^3\] This shows that the solubility product \(K_s\) in this particular case is a third-degree power function in the amount of moles of solids that dissolves per liter. Given the solubility product \(K_s\) you can calculate with this formula how much substance dissolves per liter. Conversely, you can calculate the solubility product if you know the ion concentration in the saturated aqueous solution.
\(\phantom{x}\)
Pay attention to the difference between the notions of solubility product and solubility: The latter term is about a physical property of a substance, namely, the degree to which the substance can dissolve (in terms of ion concentration in a saturated solution), while the first term is an equilibrium constant of a chemical reaction.
\(\phantom{x}\)
We give a concrete example of the calculation of solubility.
Use the below calculator for computations.
In scientific E-notation: